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ORANGE EKSTRAKLASA
Dołączył: 26 Paź 2010
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Wysłany: Nie 11:56, 13 Lut 2011 |
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Metal organic radical ion salts [Fe (CpMe) 2] [M (dmit) 2] ...
(S · cm), and found the room temperature conductivity of metallic salts and organic compounds composed of the following relationship: (1) from ferrocene (ferrocene or cobalt) cations and [M (rant):] anionic salt formed at room temperature 10S · cm conductivity orders of magnitude: while this article with IM (dmit) =] anion analogues (1 ~ 3) at room temperature conductivity in between 10 ~ 10S · cm, increased by 3 to 7 orders of magnitude. The reason may be the [M (dmit):] ions containing sulfur atoms l0 months, an increase of intermolecular charge interactions with the rules. (2) in the I-M (dmit)] anion, containing d. Electronic configuration of gold nose-ion Ni (I), Pd (I), Pt (I) compounds (1 ~ 4), the conductivity is relatively high, while the other d electrons with the metal ions Cu (I),[link widoczny dla zalogowanych], Co ( I) and other compounds (5,6) is the lower electrical conductivity. Containing [M (rant):] a similar salt anion has a similar situation [. This is because the electronic configuration of the metal into a flat square with the permanent type with complex anions, the enhanced role of conjugation,[link widoczny dla zalogowanych], more conducive to different molecular charge Q phase. Interaction and delivery. (3) are the same trampling sandwich containing cationic compounds (1 ~ 3) than with cationic mixed sandwich compounds (4 to 6) of electricity. Conductivity is higher. The reason is also worth further study. 『I l l D also tested the compounds of nitrogen and 2 from the transition to the change in room temperature conductivity, the results conductivity decreased with temperature and 1 till the small, the performance characteristics of the semiconductor. In addition,[link widoczny dla zalogowanych], I tried ear 2 at different temperatures of magnetic susceptibility,[link widoczny dla zalogowanych], indicating that the compound is paramagnetic material clear.
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