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ORANGE EKSTRAKLASA
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 Wysłany: Pią 23:27, 11 Lut 2011 |
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Solid state reaction Porphyrin Complexes
Does not exist, but there benzo c-H benzene plane bending vibration of l090 and l099cm bands. z. 4H edge resonance HPMPP porphyrin free base, the median chemical shift of hydrogen on the benzene case of 7.1O, 7.23,1 O24 Chemical climbing threshold V01.177.25, 7.38,7.90, 8.07 and 8.12 (I6H) {methoxy on the benzene ring hydrogen 4.06 (9H) {border slightly on the porphyrin ring oxygen as 8.65,8.80,8.90 (8H) { hole in the porphyrin ring on the N-H hydrogen as a 2.8O. Generate complex Lu (HPMPP) acac, due to the N-H on the hydrogen is replaced by rare earth ions,[link widoczny dla zalogowanych], the peak disappeared and the emergence of a 2.8O 2.25 peak, as the coordination of methyl acetylacetone ring hydrogen (6H) of the signal . These results indicate that porphyrin and acetylacetone have been with the Center for rare earth ions. After the formation of the complex,[link widoczny dla zalogowanych], other bands have widened. TNTBP porphyrin free base, the signal 7.24 ~ 7.80 for the different hydrogen on the indole ring due to (16H), 8.1O ~ 8.90 for the naphthalene ring due to the hydrogen (28H), generated with material Er (TNTBP) acac, after a 1.12 peak disappears,[link widoczny dla zalogowanych], the signal appears 2.23 for the coordination of methyl acetylacetone rings induced by hydrogen, indicating that the acetyl acetone, and rare earth ions.
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